Aqueous solution and the phase diagram,
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London :
E. Arnold & Co.,
[1946]
London, E. Arnold & Co [1946] London, E. Arnold & co [1946] London, E. Arnold [1946] |
| Subjects: |
Table of Contents:
- SALT PAIR DIAGRAM APPLIED TO EVAPORATION: Pictorial projection for evaporation of water
- Orthogonal projection for evaporation of water
- JANECKE'S PROJECTION: Janecke's projection for evaporation of water
- Advantages of Janecke's projection
- Janecke's projection plus water
- Janecke's projection plus water - simplified
- General survet of Janecke's diagram
- Janecke's diagram with incongruent point
- Heating and cooling
- PRACTICAL EXAMPLES USING JANECKE'S PROJECTION: Preparation of potassium nitrate from sodium nitrate and potassium chloride
- Double salts and hydrates
- Addition of a salt
- Changing the temperature
- THE FIVE-COMPONENT SYSTEM : FOUR SALTS AND WATER: Four salts with a common ion
- Quinary sustem with reciprocal salt pairs
- The quinary system, Na, K, SO4, NO3, Cl, water at 75 C
- Plotting the diagram within the prism
- Projection of the quinary with quantitative examples
- General notes on the quinary system
- GIBB'S PHASE RULE: Binary systems
- Ternary systems
- Quarternary systems
- The concentration variable
- TWO-COMPONENT DIAGRAMS: A simple case without hydrates
- With hydrate formation
- With hydrates but without eutectics (incongruent melting points)
- Retrograde solubility
- A more complicated case
- SOME PRACTICAL APPLICATIONS: Crystallization
- Purification of crystals
- Desiccation of crystals (solid processes)
- Liquid processes
- Concentration by removal of ice
- Solid fields
- HOW TO USE TRIPLE CO-ORDINATES: Triple co-ordinate lattices
- To plot a solubility curve on triple co-ordinates
- HOW TO READ THREE-COMPONENT DIAGRAMS: The interpretation of a simple diagram
- The interpretation of a diagram with double salts
- The interpretation of a diagram with hydrate
- A more complicated diagram
- Acids and bases instead of salts
- PRACTICAL APPLICATION OF THREE-COMPONENT DIAGRAMS: Precipitation
- Evaporation and dilution
- Addition of a salt
- Addition of a salt to a system containing a hydrate
- Altering the temperature
- A series of operations
- Isothermal invariant point in field of pure salt at lower temperature
- A quantitative example of a cyclic process
- DETERMINATION OF SOLUBILITY FOR PHASE DIAGRAMS: Method of wet residues
- The synthetic complex method
- Apparatus
- Thermal analysis
- Notes on three- and four-component systems
- Solid solution
- THE RECIPROCAL SALT PAIR: The base of the pyramid
- Plotting the point within the pyramid
- Orthogonal projection (the plan)