Diastereoselective and enantioselective synthesis of P-stereogenic syn-phosphiranes /
"Enantio- and diastereoselective synthesis of syn-Mes*PCH₂CHR (R = Ph, Me, Et, Ch₂OMe; Mes* = 2,4,6-(t-Bu)₃C₆H₂ was accomplished by the reaction of enantiomerically enriched epoxides with LiPHMes* followed by addition of tosyl chloride. Evidence for the alcoholate (Mes*PCH₂CHRO⁻) and toslyate...
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Format: | Thesis Book |
Language: | English |
Published: |
2013
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